B改性钒钛催化剂低温NH_3-SCR还原NO_x

选择性催化还原(SCR)技术是降低柴油机NO_x排放的常用技术,其核心部件为催化剂.目前最广泛使用的催化剂为V_2O_5/TiO_2催化剂,但其存在一些缺点,如低温活性不佳、活性温度窗口较窄等.为了解决该催化剂存在的上述一系列问题,我们对V_2O_5/TiO_2催化剂进行改性处理.采用溶胶-凝胶法和浸渍法制备了B改性的V_2O_5/TiO_2催化剂,在标准工况下,在催化剂活性测试平台上对B改性后的催化剂进行活性测试实验,采用XRD、BET和NH_3-TPD对催化剂结构进行表征.实验结果表明B改性能有效增大催化剂的比表面积和孔容,使催化剂表面弱酸量增加,进而表现出较高活性和稳定性.此外,研究了空速、氧气浓度、氨氮比以及SO_2和H_2O(g)对催化剂选择性催化还原NO_x的影响.结果表明,改性催化剂具有较好的抗硫、抗水中毒能力.     

Improvement in the light conversion efficiency of silicon solar cell by spin coating of CuO,ZnO nanoparticles and CuO/ZnO mixed metal nanocomposite material

Synthesis of pure Zinc oxide (ZnO), Copper oxide (CuO) nanoparticles (NPs) and their (ZnO/CuO) nanocomposites (NCs) in 1:1 M ratio were successfully prepared by co-precipitation method. The structural properties of the as synthesized nanoparticles and nanocomposite materials were investigated using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and X-ray diffraction (XRD) techniques. Optical band-gap studies were done using UV–Visible absorption spectroscopy. Photovoltaic properties of pure ZnO NPs, CuO NPs and ZnO/CuO NCs coated over a single-crystalline silicon solar cell were carried out to compare improvement of light-conversion efficiency in coated solar cell. The maximum light conversion efficiencies were found to be of 8.02% for CuO (3 mg/ml concentration) and 7.28% for ZnO NPs (3 mg/ml concentration), whereas that of mixed metal nanocomposite CuO/ZnO NCs was found to be 7.62%. at very low concentration of 1 mg/ml. This indicates with low concentration of mixed metal NCs an improvement in light efficiency can be obtained. The enhancement in efficiency could be due to formation of p - n heterojunction by CuO/ZnO NCs composites which enhances the number of electrons and holes participating in conduction on the surface.     

聚3-己基噻吩：非富勒烯太阳能电池中的量子效率损失和电压损失

聚3-己基噻吩(P3HT)以其合成工艺简单、成本低廉的优势,成为有机光伏领域中最具吸引力的电子给体材料之一。然而,目前P3HT: 非富勒烯太阳能电池的光伏性能仍然较差。在本工作中,我们证明了与P3HT: 富勒烯太阳能电池相比,较快的电荷转移态的非辐射衰减速率(K_nr)是导致P3HT: 非富勒烯太阳能电池中较低的量子效率和较高的电压损失的原因。然后,我们研究了基于非富勒烯受体ZY-4Cl的太阳能电池的工作机理。研究结果表明与P3HT: 非富勒烯体系相比,P3HT: ZY-4Cl中K_nr的降低改善了器件的量子效率,同时降低了电压损失。K_nr降低的原因可以部分归因于电荷转移态能量的增加。此外,给体分子和受体分子之间的距离(DA间距)的增大也是K_nr减少的重要原因。因此,我们得出结论：为了提高P3HT太阳能电池的性能,需进一步降低器件的K_nr,这可通过增加活性层中的DA间距来实现。     

应用于染料敏化太阳能电池的基于染料R6的含有不同吸电子基团的有机染料的理论研究

Dye-sensitized solar cells (DSSCs) are the most promising alternatives to traditional fossil energy because of their advantages of low production cost, facile structure, relatively low environmental impact, relatively high photoelectronic absorption efficiency, and overall high efficiency. In addition, several studies on sensitizers as vital components have been conducted over the last three decades. Compared to metal dyes, metal-free organic dyes have been considered as promising candidates because of their simple fabrication, multiple structures, high molar absorption coefficients, easily tunable properties, and environmental friendliness. In this study, we systematically investigated the optoelectronic properties of six metal-free organic donor-acceptor dyes (RD1–6) derived from the known dye R6 by using the density functional theory (DFT) and time-dependent DFT methods. Cell performance parameters were discussed, including the geometrical and electronic structures, absorption spectrum, adsorption energy, light harvesting efficiency (LHE) curve, predictive short circuit current density (J_sc^Pred.), predictive open circuit voltage (V_oc^Pred.), and theoretical power conversion efficiency (PCE). Results revealed that all the designed dyes exhibited high theoretical PCE. In particular, dyes RD1, 2, and 4–6 showed greater conjugations, and dyes RD1–3 had smaller energy gaps than those of the reference dye. In addition, dyes RD1–3, 5, and 6 exhibited better light harvesting capacities that covered the entire visible region and extended to the near-infrared region with obviously red-shift maximum absorption wavelengths (λ_max), wider LHE curves, and higher J_sc^Pred. as compared to the reference dye. It was critical that dyes RD1 and 2 not only have greater conjugations and narrow band gaps but also good light harvesting capacities with more than 56-nm red-shift maximum absorption wavelengths and broadened LHE curves than those of the reference dye. Notably, mainly because of an average increment of 12.0% of J_sc^Pred., a remarkable increment of the theoretical power conversion efficiency was observed from 12.6% for dye R6 to 14.1% for dyes RD1 and 2. Thus, dyes RD1 and 2 exhibited superior cell performances and could be promising sensitizer candidates for highly efficient DSSCs. These results could be used to guide effective synthetic efforts in the discovery of efficient metal-free organic dye sensitizers in DSSCs.     

Boundary and initial fluctuation effect on dynamic behaviour of a laminated solid

Two problems will be studied in this contribution. First, we analyse some phenomena which take place in a laminated solid and are caused by a fluctuation of time-dependent boundary tractions. Second, we investigate the transient effect of initial displacement fluctuations on the behaviour of a laminate. To solve the above problems we propose a new macroscopic 3D model for investigations of initial-boundary value problems in elastodynamics of a laminated medium.     

Mixing in horizontally heterogeneous flows

An experimental study of mixing across density interfaces produced by laterally heterogenous turbulence is presented in this paper. The turbulence is generated by a flow or air bubles rising through a density interface produced by brine and fresh water. The mixing efficiency, , of the process is measured comparing the increase in potential energy with the available kinetic energy. We find that there is a decrease in the global mixing efficiency of the process with the length of the tank, the shape of (Ri) depends also on the air flow producing the turbulence, showing a geometrical limit to the ammount of kinetic energy which may be used for mixing.     

Dynamic load and inflation pressure effects on contact pressures of a forestry forwarder tire

A Trelleborg Twin 421 Mark II 600/55-26.5 steel-reinforced bias-ply forwarder drive tire at inflation pressures of 100 and 240 kPa and dynamic loads of 23.9 and 40 kN was used at 5% travel reduction on a firm clay soil. Effects of dynamic load and inflation pressure on soil–tire contact pressures were determined using six pressure transducers mounted on the tire tread. Three were mounted on the face of a lug and three at corresponding locations on the undertread. Contact angles increased with decreases in inflation pressure and increases in dynamic load. Contact pressures on a lug at the edge of the tire increased as dynamic load increased. Mean and peak pressures on the undertread generally were less than those on a lug. The peak pressures on a lug occurred forward of the axle in nearly all combinations of dynamic load, inflation pressure, and pressure sensor location, and peak pressures on the undertread occurred to the rear of the axle in most of the combinations. Ratios of the peak contact pressure to the inflation pressure ranged from 0 at the edge of the undertread for three combinations of dynamic load and inflation pressure to 8.39 for the pressure sensor on a lug, near the tire centerline, when the tire was underinflated. At constant dynamic load, net traction and tractive efficiency decreased as inflation pressure increased.     

Kinetics of microcrack blunting ahead of macrocrack approaching shear wave speed

The fracturing of glass and tearing of rubber both involve the separation of material but their crack growth behavior can be quite different, particularly with reference to the distance of separation of the adjacent planes of material and the speed at which they separate. Relatively speaking, the former and the latter are recognized, respectively, to be fast and slow under normal conditions. Moreover, the crack tip radius of curvature in glass can be very sharp while that in the rubber can be very blunt. These changes in the geometric features of the crack or defect, however, have not been incorporated into the modeling of running cracks because the mathematical treatment makes use of the Galilean transformation where the crack opening distance or the change in the radius of curvature of the crack does not enter into the solution. Change in crack speed is accounted for only via the modulus of elasticity and mass density. For this simple reason, many of the dynamic features of the running crack have remained unexplained although speculations are not lacking. To begin with, the process of energy dissipation due to separation is affected by the microstructure of the material that distinguishes polycrystalline from amorphous form. Energy extracted from macroscopic reaches of a solid will travel to the atomic or smaller regions at different speeds at a given instance. It is not clear how many of the succeeding size scales should be included within a given time interval for an accurate prediction of the macroscopic dynamic crack characteristics. The minimum requirement would therefore necessitate the simultaneous treatment of two scales at the same time. This means that the analysis should capture the change in the macroscopic and microscopic features of a defect as it propagates. The discussion for a dual scale model has been invoked only very recently for a stationary crack. The objective of this work is to extend this effort to a crack running at constant speed beyond that of Rayleigh wave. Developed is a dual scale moving crack model containing microscopic damage ahead of a macroscopic crack with a gradual transition. This transitory region is referred to as the mesoscopic zone where the tractions prevail on the damaged portion of the material ahead of the original crack known as the restraining stresses, the magnitude of which depends on the geometry, material and loading. This damaged or restraining zone is not assumed arbitrarily nor assumed to be intrinsically a constant in the cohesive stress approach; it is determined for each step of crack advancement. For the range of micronotch bluntness with 0 < β < 30° and 0.2 σ_∞/σ₀ 0.5, there prevails a nearly constant restraining zone size as the crack approaches the shear wave speed. Note that β is the half micronotch angle and the applied stress ratio is σ_∞/σ₀ with σ₀ being the maximum of the restraining stress. For σ_∞/σ₀ equal to or less than 0.5, the macrocrack opening displacement COD is nearly constant and starts to decrease more quickly as the crack approaches the shear wave speed. For the present dual scale model where the normalized crack speed v/c_s increases with decreasing with the one-half microcrack tip angle β. There prevails a limit of crack tip bluntness that corresponds to β 36° and v/c_s 0.15. That is a crack cannot be maintained at a constant speed if the bluntness is increased beyond this limiting value. Such a feature is manifestation of the dependency of the restraining stress on crack velocity and the applied stress or the energy pumped into the system to maintain the crack at a constant velocity. More specifically, the transitory character from macro to micro is being determined as part of the unknown solution. Using the energy density function dW/dV as the indicator, plots are made in terms of the macrodistance ahead of the original crack while the microdefect bluntness can vary depending on the tip geometry. Such a generality has not been considered previously. The macro-dW/dV behavior with distance remains as the inverse r relation yielding a perfect hyperbola for the homogeneous material. This behavior is the same as the stationary crack. The micro-dW/dV relations are expressed in terms of a single undetermined parameter. Its evaluation is beyond the scope of this investigation although the qualitative behavior is expected to be similar to that for the stationary crack. To reiterate, what has been achieved as an objective is a model that accounts for the thickness of a running crack since the surface of separation representing damage at the macroscopic and microscopic scale is different. The transitory behavior from micro to macro is described by the state of affairs in the mesoscopic zone.     

混合层强化混合的数值研究

受 Ｗａｎｇ ＆ Ｆｉｅｄｌｅｒ（１９９７）的实验的启发，采用高阶精度的差分格式，通过数值模拟的方法，研究了二维混合层及限于两平板间的二维混合层（二维受限混合层）入口处加振动对提高混合层混合效率的作用．计算结果表明：对二维混合层，振动的频率越低，在混合层中产生的大尺度涡结构的尺度越大，在频率很低时，涡具有相似性；对限于两平板间的二维混合层，在一定的振动频率下，混合层中产生的涡较大而且破碎得也较好，这将有利于混合．这一结论与 Ｗａｎｇ ＆ Ｆｉｅｄｌｅｒ（１９９７）的实验观测到的结果是一致的．     

Concepts and realization of microstructure heat exchangers for enhanced heat transfer

Microstructure heat exchangers have unique properties that make them useful for numerous scientific and industrial applications. The power transferred per unit volume is mainly a function of the distance between heat source and heat sink—the smaller this distance, the better the heat transfer. Another parameter governing for the heat transfer is the lateral characteristic dimension of the heat transfer structure; in the case of microchannels, this is the hydraulic diameter. Decreasing this characteristic dimension into the range of several 10s of micrometers leads to very high values for the heat transfer rate.

Another possible way of increasing the heat transfer rate of a heat exchanger is changing the flow regime. Microchannel devices usually operate within the laminar flow regime. By changing from microchannels to three dimensional structures, or to planar geometries with microcolumn arrays, a significant increase of the heat transfer rate can be achieved.

Microheat exchangers in the form of both microchannel devices (with different hydraulic diameters) and microcolumn array devices (with different microcolumn layouts) are presented and compared. Electrically heated microchannel devices are presented, and industrial applications are briefly described.